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Tag Archives: Hydraulic Fracturing

Patents on Treatment of Hydraulic Fracturing Water

Posted in Cleaning Up Hydraulic Fracturing; Uncategorized

We continue to monitor patent literature for water and liquid treatment technologies related to hydraulic fracturing (see our October 7, 2012 blog entry, for example). We did not see as many granted patents in 2010 and 2011 compared to 2012 (likely a trend reflecting the increased importance of hydraulic fracturing in recent years). One exception was US Patent No. 7,722,770 granted May 25, 2010 (the listed assignee is Anticline Disposal, LLC). Anticline now has five granted patents, best we can tell (8,105,488; 7,722,770; 7,628,919; 7,527,736; and 7,510,656). The processes appear to link to nanotechnology via nanofiltration and reverse osmosisSee also this link. Nanotechnology continues to be a prominent theme in new hydraulic fracturing technologies although many of these nano-HF patent filings are not included in the 977 nanotechnology patent class.

For the Anticline ’770 patent, the abstract indicates:

ABSTRACT: Systems and methods have been developed for treating the waste water contaminated with methanol and boron in addition to other contaminants. The systems and methods allow specifically for the removal of the methanol and boron without the addition of significant chemicals to raise the pH. The water is treated by removing the methanol via biological digestion in a bioreactor, separating a majority of the contaminants from the water by reverse osmosis and removing the boron that passes through the reverse osmosis system with a boron-removing ion exchange resin.

Recent U.S. Patents Granting for Treatment of Hydraulic Fracturing Waters

Posted in Cleaning Up Hydraulic Fracturing; Cleantech; Patent; Water

We continue to monitor patent literature for water and liquid treatment technologies related to hydraulic fracturing. This technology is especially important for western Pennsylvania, the center of the Marcellus Shale region. Yesterday, for example, I listened to a speech by Carnegie Mellon University’s president, which stressed the importance of this technology.  CMU has a new energy center which will include work in this area. CMU has also published a research guide on hydraulic fracturing.

Recent patents in 2012 which relate directly or indirectly to this subject include 8,273,320 (FracPure Holdings); 8,226,832 (NCH Ecoservices); 8,211,296 (NCH Ecoservices); 8,171,993 (Heat On-the-Fly); 8,158,097 (FracPure Holdings); 8,119,007 (MIT); 8,110,115 (Ibex); 8,105,488 (Anticline Disposal); 8,105,492 (Baker Hughes); and 8,132,632 (ConocoPhillips).

Integrated Water Technologies has an interesting, lengthy video which summarizes the FracPure process. The process includes the water supply, water treatment, and extracting solids from the treated waters.

Hydraulic Fracturing Patent Literature on the Rise (With Nanotech Contributions)!

Posted in Cleaning Up Hydraulic Fracturing; Patent; Water

Patent filings which refer to hydraulic fracturing are on the rise. In fact, the number appears to have almost doubled in the past five years. This is based on a review of the published patent applications at the USPTO web site. In 2012, pro-rated as of today, there should be about 473 patent applications publishing. In 2007, that number was only 246. From 2008-2010, the number rose to about 355 each year, and then rose dramatically in 2011 to 421.

Nanotechnology continues to be a source of innovation in this and related technologies. See, for example, Abstract below US Patent Publication 2012/0190598 published July 26, 2012 to Pure Liquid Solutions, LLC, on “Metallic Nanoparticle Biocide in Industrial Applications.”

Abstract
A method includes providing and adding a measured dose amount of manufactured metallic nanoparticle material to a carrier material for pre-treatment of the carrier material prior to use of the carrier material and the manufactured metallic nanoparticle material in the sub-surface earth activity. Another method includes accessing a sub-surface earth opening used with a sub-surface earth activity, introducing an amount of manufactured metallic nanoparticle material into the sub-surface earth opening, and treating a sub-surface earth condition present at a sub-surface earth location accessible via the sub-surface earth opening. The sub-surface earth condition is treated with the manufactured metallic nanoparticle material. Another method includes accessing a product from a sub-surface earth location that is extracted in conjunction with the sub-surface earth activity, measuring and introducing a dose amount of manufactured metallic nanoparticle material with the product from the sub-surface earth location.

Nanotechnology Patent Filing Explosion Continues on a Record Pace in 2012

Posted in Cleaning Up Hydraulic Fracturing; Licensing; Patent; U.S. Patent Reform

We confirm that a nanotechnology patent filing explosion continues at a record pace in 2012 as we enter the final trimester of the year. On July 8, 2012, we reported that the USPTO was on pace to publish a record number of class 977 nanotechnology patent applications (over 4,000). This was also noted in past postings and reflects a solid trend. We checked again today and confirm that the current projection to end of the year remains at over 4,000 (4,043). The broad variety of technology in the filings is startling and in places unconventional. For example, US Patent Publication 2012/0221268 (the last application to publish) relates to quantum computing and lists Microsoft as assignee. Hydraulic fracturing is increasingly referred to in this body of patent literature as there are 16 such publications this year which is double the number compared to the prior three years combined (e.g., Halliburton’s US Patent Publication 2012/0220504).

Hopefully, as many of these patent filings as possible will serve useful commercial purposes and facilitate investment from the private sector as well as from government. The licensing of these patent filings can be analyzed for use in policy formulation and business development. Certainly, the on-going miniaturization of electronic devices – a hot patent topic these days with the Apple v. Samsung developments - will require more developments in nanotechnology including, for example, better batteries, power management, semiconductors, and displays.  Clearly, many of the  patent filings find applications related to energy, electronics, and bio nanotechnology.

In addition, hopefully the quality of filings remains solid despite the pressures to file applications. Finally, (hopefully!), patent reform will function to improve the patent system and encourage investment, particularly as it applies to nanotechnology inventions.

New U.S. Patent Filings Publish on Treatment of Hydraulic Fracturing Water, a Growth Industry

Posted in Cleaning Up Hydraulic Fracturing

In 2012, at least five patent applications have published related to treatment of hydraulic fracturing water including waste water. We expect this number to grow. A variety of assignees are evident. Lux Research recently published a report on the subject of water treatment. Examples of patent filings include:

General Electric’s 2012/0097614 (interesting: DOE funding is evident);

Encana Corp.’s 2012/0085236 (Calgary);

Aquionics, Inc.’s 2012/0070339 (Kentucky);

Chevron’s 2012/0024525; and

Don Nevin’s 2012/0012307.

EPA’s New “Draft Guidance” for Fracking: Oil/Gas Industry Generally Pleased, But Caution Is Advised

Posted in EPA

In the Federal Register of May 10, 2012, U.S. EPA issued long-awaited “Draft Guidance” for regulating the highly controversial and rapidly-growing practice known as hydraulic fracturing — or “fracking” — for natural gas and oil. See 77 FR 27451. EPA is requesting written public comments on the draft guidance (with a deadline of July 9, 2012). 

The practice of fracking is credited for greatly expanding the volumes of natural gas produced in the U.S. — and driving down the price to near-record low levels. But many concerns about health and environmental impacts (such as groundwater contamination and air emissions) have been raised. 

While EPA has begun regulating various aspects of fracking (such as air emissions under the Clean Air Act), by far the most closely watched effort is the prospect of EPA regulation under the Safe Drinking Water Act (SDWA). If fracking operations become subject to the permitting process of the SDWA’s “underground injection control” (UIC) program, each new proposed project could suffer great delays (and potential rejection). This is because such permits can only be issued after a public notice and comment process, and issued permits are subject to judicial review. Thus opponents of a proposed fracking project (and many projects are vigorously opposed) could use the legal process produce great delays or even kill a project.

Not surprisingly, EPA’s SDWA guidance development process has involved plenty of lobbying from industry and environmental interest groups. Probably the most contentious issue is how EPA would define “diesel.”

Why is EPA’s definition of “diesel” so critical? In the fracking process, fluids are injected at high pressure to fracture underground rock and shale formations and help extract gas or oil that would otherwise be unobtainable. In 2005, Congress amended the SWDA to provide that EPA could not regulate fracking under the SDWA UIC program except for projects where “diesel” is the fluid used in the injection process. Thus fracking with “diesel” can be regulated under the SDWA; fracking without “diesel” cannot.

Since 2005, industry groups have reported that very few (if any) fracking projects utilize diesel as it is commonly defined (such as No.2 fuel oil). Thus, if EPA were to define “diesel” with the word’s common usage, very little fracking would be subject to the SDWA UIC program.

Recognizing this, environmental interest groups and their Democrat allies in Congress had been urging EPA to issue a very broad definition of diesel. They argued that since diesel contains the “BTEX compounds” (i.e., benzene, toluene, ethylbenzene, and xylenes), any fracking activity with fluids that contain any of those compounds should be regulated. In other words, they argued that any fluid that contained any compound that diesel contained should be defined as “diesel” for purposes of the SDWA. If this extremely broad definition were to prevail, a great majority of the fracking projects in the U.S. would apparently be regulated under the SDWA UIC program.

At various stages in the guidance development project, key EPA staffers had made statements indicating sympathy with the broad definition favored by environmental groups and certain Democrats in Congress. In the newly issued draft guidance, however, EPA has chosen to stick with a more traditional definition of “diesel,” thus pleasing the industry groups. EPA in fact notes that its data shows that probably less than 2% of fracking undertaken as of 2011 used “diesel” as EPA’s new draft guidance defines it.

This limited coverage does not diminish the significance of the draft guidance, however. For one thing, guidance is only “draft” and EPA specifically requests comments (due July 9 as noted above) on whether the definition of “diesel” should be broadened. Moreover, the new draft guidance contains many recommendations for procedures and practices to be followed for fracking operations. Many states are moving in the direction of regulating fracking, and they can be expected to look to the EPA “guidance” in developing their own practices and procedures. Thus interested parties on all sides of the issue would be well advised to study the draft guidance and submit comments.

Recent Hydraulic Fracturing Patenting Shows Connections With Cleantech and Nanotech

Posted in Cleaning Up Hydraulic Fracturing; Cleantech; Patent; Water

Hydraulic fracturing (HF) has become a substantial economic force and the subject of strong policy debate. HF has several connections to cleantech, including issues of water treatment and disposal. Recent patents related to water and cleantech include, for example, USP 8,119,007 to MIT, 8,110,115 to Ibex, and 8,105,488 to Anticline Disposal. U.S. Patents that refer to HF now grant at almost twice the rate as 2009 and before. This year, already, 41 have granted, and the number in 2011 was 224 and in 2010 was 257.

Nanotechnology also should become part of the search for HF technical solutions. USP 8,105,492 to Baker Hughes (“Methods for Recharging Nanoparticle-Treated Beds”) relates heavily to nanotechnology. The patent was not classified as a 977 nanotechnology patent, however. The Abstract shows:

Abstract

Nanoparticle-treated particle packs, such as sand beds, may effectively filter and purify liquids such as waste water. Proppant beds treated with nanoparticles may fixate or reduce fines migration therethrough. When tiny contaminant particles or fines in these fluids flow through the nanoparticle-treated bed or pack, the nanoparticles will capture and hold the tiny contaminant or fines particles within the pack due to the nanoparticles’ surface forces, including, but not necessarily limited to van der Waals and electrostatic forces. Nanoparticle-treated beds or packs may be recharged by contacting the bed with an inorganic acid (but not hydrofluoric acid) or an organic acid, and optionally followed by subsequent treatment with hydrofluoric acid. This treating substantially removes the nanoparticles and the fine particulates that have been removed from a fluid (e.g. wastewater being treated, produced fluids in a formation, etc.). The particle pack may then be re-treated or recharged with nanoparticles.

Domestic Inventing in Hydraulic Fracturing Arts

Posted in Cleaning Up Hydraulic Fracturing; Cleantech; Patent; Water

President Obama’s recent State of the Union address spoke of domestic oil and gas industry including shale gas (“American-made energy”). A leading but controversial technology for this industry is, of course, hydraulic fracturing. A brief review of the patent literature for 2012 confirms that inventors in this area for US patent filings are largely from the US. In a global economy, such domestic concentration for inventorship is somewhat unusual. The concentration of this innovation in the U.S. should be monitored.

As of today, in 2012, 38 patent publications refer to “hydraulic fracturing.” Of these, 27 (71%) list all U.S. inventors, and 32 (84%) list all U.S. inventors or list a majority of inventors as residing in the U.S.  Only 5 of the 38 (13%) list all non-U.S. inventors. The leading state for inventors is Texas.

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Nanotechnology in Hydraulic Fracturing Innovation – 2011 Developments

Posted in Cleaning Up Hydraulic Fracturing; Patent; Water

An important development to watch is how nanotechnology can be used as an innovation tool for hydraulic fracturing. See, for example, our prior blog posts of July 20, June 24, and June 5, 2011. The problem starts with nano: valuable carbonaceous materials are trapped in dense pore rock with pores scaling down to the nanoscale. How to get it out?

The problem continues with how to handle the waste water – nano is also important for this issue. The EPA provides an overview of these important commercial, environmental, and technical issues.

A number of hydraulic fracturing patent publications in 2011 were accorded the 977 nanotech classification. For example, on December 1, 2011, a patent application published related to nanodispersion well serving fluids including nanoparticles. PTO assignment recordation records show the application is now owned by Baker Hughes. In addition, on September 29, 2011, Chevron USA had published an application related to nanoparticle completion fluids.

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Hydraulic Fracturing Innovation Updates

Posted in Cleantech; Patent

We note some new developments in hydraulic fracturing (HF):

1)  Pennsylvania’s long awaited HF Commission Report finally issued last week (July 22, 2011).

2)  The Report is 137 pages.  The purpose of this Commission Report is not to focus on HF technology, but the report does provide extensive technical background.  The report shows, for example, at Figure 17 (page 28) a picture of the shale pores which reveals the sub-micron (nanoscale) nature of the problem of getting natural gas to pass through these openings.  Pore size analysis is an important aspect of nanotechnology generally which is often overlooked (e.g., "micropores," versus "mesopores," versus "macropores").  Figure 17 and its supporting discussion show typical pore size of 0.000019 inch diameter pores, which is 482 nm.

3) Today, six new HF patent applications published at the US PTO continuing a strong innovation trend in a "hot" commercial area.  Three of the six are more environmentally motivated.  Two relate to the type of proppant.  The sixth is for use of seismic data. 

HF technology will continue to evolve and improve – at a rapid rate - and regulatory action will need to keep pace to be effective and balance the need to commercialize and the need to protect the environment.  I would have suggested that at least several pages of a lengthy report such as this would include emerging innovation which may impact the HF situation.

 

Another Shale Boom: Hydraulic Fracturing and Shale Oil This Time

Posted in Cleantech

Hydraulic fracturing continues to present new innovation opportunities on the energy scene which can/will transform the economy. See, for example, the front page report in the May 28, 2011 New York Times (“Oil Hidden in Shale Sets Off a Boom in Texas“).

According to this report, hydraulic fracturing is now being used to recover oil from “low-quality” shale in South Texas including the Eagle Ford site. The Times reports that more than a dozen companies plan to drill up to 3,000 wells in the next 12 months. Moreover, the fields were thought to be valueless five years ago, per the Times. However, hydraulic fracturing and horizontal drilling were also developed for use with oil extraction, despite the larger molecules in oil compared to natural gas. Small-scale morphology including small diameter microholes and/or nanopores play a critical role in the extraction, and the small pore size can affect extraction. Of course, water remains a key issue as these developments move forward, particularly in areas of drought and limited water supply.

The micro- and nano-scale aspects of shale oil and gas extraction should be the subject of intense government-sponsored research, as well as research on solutions to water problems.

Business Method Patenting and Hydraulic Fracturing in Marcellus Shale

Posted in Cleantech

Today’s Pittsburgh Post-Gazette has a very important, interesting article on using innovative technology like GPS to track frack water, Tracking Fracking Water Goes High-Tech. We are measuring whether business method type patents are being sought in this space. Business method patents can be economically valuable but can also present high levels of legal risk and uncertainty. Stay tuned.

More Evidence for Rapid Growth in Hydraulic Fracturing Patenting

Posted in Cleantech; Patent

PCT patent publications also show a rapid rise in hydraulic fracturing (HF) patenting, much like for U.S. patent publications. For example, from 2001 to 2006, 5-10 HF PCT patent applications published per year. Starting in 2007, this jumped unexpectedly to 22 and the trend has been maintained since then. In other words, the patent publication rate doubled starting around 2007.

For purposes of this blog, HF patents were those including the term in the abstract, which is one form of isolating patents which focus heavily on HF. In particular, 2010 showed 17 HF PCT patent publications; 2009 showed 20 HF patent publications; 2008 showed 19 HF publications, and 2007 showed 22 patent publications.
 

Du Pont and Schlumberger Lead Hydraulic Fracturing Race for 2010-2011 as HF Patenting Accelerates Rapidly

Posted in Cleantech; Patent

E.I. du Pont is leading the hydraulic fracturing (HF) patent race by one measure. So far, in 2010-2011, a total of 41 U.S. patents have issued wherein "hydraulic fracturing" is mentioned in the patent abstract (one lead indicator for relevant HF patents). Du Pont has the largest number of these patents, 11. The second place company is Schlumberger Technology Corp. which has 8. In third place is Baker Hughes (7), and next is BJ Services (5). No other company has more than two patents. Clearly, patenting in this area is concentrated in select companies. Only one university received a patent (Stanford).

The HF patenting rate is increasing rapidly. Whereas, since 2004, typically 10 -13 patents issue per year, in 2010, 33 issued. So far, in 2011, the number of patents has already exceeded 25 and is projected to again surpass that of prior years.
 

Update on U.S. Patent Explosion for Hydraulic Fracturing Technology

Posted in Cleantech; Patent

The impact of hydraulic fracturing on cleantech is a critical subject central to the United States’ energy policy. Meanwhile, inventors continue to file for patent protection on hydraulic fracturing (HF) technology at an exploding rate. We previously reviewed granted U.S. patents in our March 20, 2011 HF entry. Here, we note published application trends. Compared to granted U.S. patents, published applications represent more recent filing trends. Again, we see an explosion.

Since 2008, over 300 patent publications publish each year mentioning hydraulic fracturing. Before 2006, this number was less 200. In essence, the rate of patenting nearly doubled over the 2006-2007 time period. While not all of these patent publications focus exclusively on hydraulic fracturing, many of them do (e.g., approximately 16% include the term in the title, abstract, or claim).

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U.S. Patent Explosion for Hydraulic Fracturing Technology: Impact on Marcellus Shale

Posted in Cleantech; Patent; Water

Hydraulic fracturing (HF) continues to be a critical and controversial technology for U.S. energy policy and the larger implications of cleantech. This method can be used to recover natural gas from deep shale such as the Barnett or Marcellus Shale centered in Texas and Pennsylvania, respectively. In particular, the developments in Pennsylvania’s Marcellus Shale in the past several years have attracted much political and media attention, including environmental debate. In this post, some important patent trends are reported which illustrate how critical HF has become to the U.S. economy and innovation.

First, 2010 was a record breaking year for hydraulic fracturing at the USPTO. Patent search results showed 257 patent were issued in 2010 which referred to HF. Moreover, already in 2011, as of today, 47 more HF patents have issued which projects to over 220 in 2011 if that trend continues.
In stark contrast, from 1981 to 2003, the USPTO only issued about 50 HF patents a year. The trend was remarkably steady over these 23 years with a high of 73 in 1993 and a low of 25 in 1982.
 

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